Collect. Czech. Chem. Commun.
1979, 44, 3281-3287
https://doi.org/10.1135/cccc19793281
The reaction of polymers of 2,3-epoxypropyl methacrylate with N-(benzyloxycarbonyl) glycine and glycine tert-butyl ester
Vladimír Kellner, Jiří Čoupek and Jaroslav Kálal
Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6
Abstract
The reaction of the epoxy groups of polymers of 2,3-epoxypropyl methacrylate with N-(benzyloxycarbonyl) glycine in N,N-dimethylformamide and the reaction with glycine tert-butyl ester in benzene in the presence of 4-nitrophenol at 80°C were investigated. The rate constants were calculated for the reaction with N-(benzyloxycarbonyl) glycine. The reaction of macroporous gels of 2,3-epoxypropyl methacrylate-ethylene dimethacrylate with N-(benzyloxycarbonyl) glycine was studied.
