Collect. Czech. Chem. Commun.
1981, 46, 2557-2563
https://doi.org/10.1135/cccc19812557
Synthesis of pyrido[1,2-a]-1,3,5-triazines. Reactions of 2-pyridyl isothiocyanate with compounds containing a C=N bond
Miroslav Marchalín, Jan Světlík and Augustin Martvoň
Research Institute for Drugs, 801 00 Bratislava
Abstract
New pyrido[1,2-a]-1,3,5-triazine derivatives were prepared by the [4+2]cycloaddition reaction of 2-pyridyl isothiocyanates with isocyanate, aldimines, and N,N'-diphenylcarbodiimide. On the other hand, reaction of 2-pyridyl isothiocyanate with aliphatic carbodiimides afforded [2+2]cycloaddition products, 1,3-thiazetidines.
