Collect. Czech. Chem. Commun.
1985, 50, 1636-1641
https://doi.org/10.1135/cccc19851636
Possible use of chronopotentiometry at the interface between two immiscible liquid phases to the studies of homogeneous chemical reactions
Emanuel Makrlík
Nuclear Research Institute, 250 68 Řež
Abstract
The theoretical potential-time dependence corresponding to the electron transfer reaction proceeding at the interface between two immiscible liquid phases with the redox pairs O1/R1 in the aqueous (aq) phase and O2/R2 in the non-aqueous (non) phase, that is complicated by the reaction R1(aq) + Z(aq) → O1(aq) in the aqueous phase, has been derived under the galvanostatic conditions. Moreover, a method for the determination of the formal rate constant kf for the given homogeneous chemical reaction is proposed.
