Collect. Czech. Chem. Commun. 1993, 58, 2936-2943
https://doi.org/10.1135/cccc19932936

Asymmetric Cobaltacarboranes [6,6'-μ-R-S(1,7-C2B9H10)2-2-Co] with a Monosulfur Bridge between Ligands and HPLC Resolution of the Enantiomers

Jaromír Plešeka, Bohumír Grünera, Jiří Fuseka and Hana Votavováb

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 25068 Řež near Prague, Czech Republic
b Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 166 10 Prague 6, Czech Republic

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Other CCCC articles of these authors

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  • Bohumír Grüner*, Ivana Císařová, Josef Čáslavský, Bernard Bonnetot and David Cornu
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    2002, Vol. 67, Issue 7, pp. 953–964 [Abstract]
  • Michaela Hamerníková*, Jaroslav Havlíček, Hana Votavová and Karel Kefurt
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    2002, Vol. 67, Issue 5, pp. 622–644 [Abstract]
  • Jaromír Plešek*, Ivana Císařová and Jaroslav Bačkovský
    Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications
    2002, Vol. 67, Issue 5, pp. 569–576 [Abstract]
  • Jaromír Plešek*, Jaroslav Bačkovský, Jiří Fusek and Zbyněk Plzák
    Cyanoethylation and (Methoxycarbonyl)ethylation of Icosahedral ortho-Carborane Derivatives at Carbon Vertices via Michael Additions
    2001, Vol. 66, Issue 10, pp. 1499–1507 [Abstract]
  • Zbyněk Matušina, Radomíra Olbřímková, Hana Votavová, Josef Neumann, Martin Hradilek, Milan Souček, Petr Maloň, Milan Kodíček and Ivan Stibor*
    Linear Heptapeptides Containing DNA-Intercalators. Synthesis and Interaction with DNA
    1999, Vol. 64, Issue 9, pp. 1419–1432 [Abstract]
  • Bohumil Štíbr*, Zbyněk Janoušek, Matthew Trammell, Bohumír Grüner and Zbyněk Plzák
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    1999, Vol. 64, Issue 6, pp. 971–976 [Abstract]
  • Daoud Naoufal*, Bernard Bonnetot, Henri Mongeot and Bohumír Grüner
    Synthesis of Bis(diphenylphosphinio)octahydro-closo-decaborates L2B10H8 (L = Ph2PH) and 1-(Diphenylphosphinio)nonahydro-closo-decaborates(1-) [1-LB10H9]- (L = Ph2PH, Ph2P(OH)) by the Palladium-Catalyzed Reaction of Ph2PH with 1-Diazononahydro-closo-decaborate(1-) [1-N2B10H9]-
    1999, Vol. 64, Issue 5, pp. 856–864 [Abstract]
  • Michal Hušák, Bohumil Kratochvíl, Petr Sedmera, Vladimír Havlíček, Hana Votavová, Ladislav Cvak, Petr Bulej and Alexandr Jegorov
    Molecular Structure of cis- and trans-Tergurides
    1998, Vol. 63, Issue 3, pp. 425–433 [Abstract]
  • Karel Kefurt, Jaroslav Havlíček, Michaela Hamerníková, Zdeňka Kefurtová and Hana Votavová
    Conformation of 5-Amino-5-deoxypentonolactams
    1997, Vol. 62, Issue 12, pp. 1919–1930 [Abstract]
  • Bohumil Štíbr, Josef Holub, Tomáš Jelínek, Bohumír Grüner, Jiří Fusek, Zbyněk Plzák, Francesc Teixidor, Clara Viñas and John D. Kennedy
    A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
    1997, Vol. 62, Issue 8, pp. 1229–1238 [Abstract]
  • Bohumír Grüner, Bernard Bonnetot and Henri Mongeot
    Synthesis of N- and B-Substituted Derivatives of closo-Amino-undecahydro-dodecaborate(1-) Anion
    1997, Vol. 62, Issue 8, pp. 1185–1204 [Abstract]
  • Andreas Franken, Jaromír Plešek, Jiří Fusek and Markus Semrau
    Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11)
    1997, Vol. 62, Issue 7, pp. 1070–1079 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Josef Holub
    Synthesis and Properties of Cobaltacarboranes with Substituted Monoatomic Bridges Between Ligands of the 6,6'-μ-RnE(1,7-C2B9H10)2-2-Co Type
    1997, Vol. 62, Issue 6, pp. 884–893 [Abstract]
  • Andreas Franken, Jaromír Plešek and Christiane Nachtigal
    Unusual Rearrangement of Naphthalene in the Synthesis of a Novel B8-B8-Bridged Derivative in the [(1,2-C2B9H11)2-3-Co]- Series. X-Ray Structure and 11B NMR Spectra of [8,8'-μ-(CH2-C9H6)-(1,2-C2B9H10)2-3-Co]- (CH3)4N+
    1997, Vol. 62, Issue 5, pp. 746–751 [Abstract]
  • Jaromír Plešek, Andreas Franken and Roland Fröhlich
    The Structure of [6,6'-μ-S(1,7-C2B9H10)2-2-Co]-[PPh4]+
    1997, Vol. 62, Issue 1, pp. 57–61 [Abstract]
  • Jaromír Plešek, Stanislav Heřmánek, Andreas Franken, Ivana Císařová and Christiane Nachtigal
    Dimethyl Sulfate Induced Nucleophilic Substitution of the [Bis(1,2-dicarbollido)-3-cobalt(1-)]ate Ion. Syntheses, Properties and Structures of Its 8,8'-μ-Sulfato, 8-Phenyland 8-Dioxane Derivatives
    1997, Vol. 62, Issue 1, pp. 47–56 [Abstract]
  • Jiří Vohlídal, Jaromír Plešek, Jan Sedláček, Ivana Císařová, Pavel Matějka and Stanislav Heřmánek
    Cobaltacarboranylacetylene 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III): Synthesis, Characterization and Polymerization of New Substituted Acetylene
    1996, Vol. 61, Issue 6, pp. 877–887 [Abstract]
  • Zlatko Janeba, Antonín Holý, Hana Votavová and Milena Masojídková
    Intramolecular Cyclization of Some Acyclic Nucleoside Analogs
    1996, Vol. 61, Issue 3, pp. 442–457 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure
    1995, Vol. 60, Issue 8, pp. 1297–1302 [Abstract]
  • Jaromír Plešek, Farzaneh Hosseinpour Rajabi, Veena Vangani and Jiří Fusek
    Constitution and Properties of the 8,8'-μ-(H2NO)=(1,2-C2B9H10)2-3-Co Bridged Cobaltaborane
    1994, Vol. 59, Issue 6, pp. 1326–1336 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Stanislav Heřmánek, Jiří Fusek and Hana Votavová
    Constitution and HPLC Resolution of Enantiomers of the [8,4'-μ-R2N-commo-(1,2-C2B9H10)2-3-Co] Complexthe Third Isomer of Nitrogen-Bridged Bis
    1994, Vol. 59, Issue 2, pp. 374–380 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, František Mareš and Stanislav Heřmánek
    Unique Dialkylsulfonio-Methylation of the 7,8-C2B9H12(-) Ion to the 9-R2S-CH2-7,8-C2B9H11 Zwitterions by Formaldehyde and Dialkyl Sulfides. General Synthesis of the Compounds 10-R2E-7,8-C2B9H11 (E = O, S)
    1993, Vol. 58, Issue 7, pp. 1534–1547 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Petr Maloň
    Synthesis and Properties of (±)- and (+)-4-MeS-3-C2H5-1,2,3-C2CoB9H10
    1993, Vol. 58, Issue 5, pp. 1087–1092 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • Lenka Schneiderová, Oldřich Štrouf, Bohumír Grüner, Vladimír Pouzar, Pavel Drašar, Richard Hampl and Irena Kimlová
    Synthesis of o-Carboranylmethyl Ethers of Steroids as Potential Target Substrates for Boron Neutron Capture Therapy
    1992, Vol. 57, Issue 3, pp. 463–471 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Otomar Kříž, Zbyněk Plzák and Jaromír Plešek
    Triethylamine borane - a stable, efficient and safe reductant for transforming carboxylic acids to primary alcohols
    1990, Vol. 55, Issue 12, pp. 2956–2962 [Abstract]
  • Milan Drátovský, Bohumír Grüner, Ivan Horsák and Jiří Makovička
    The Na+, K+/CN-, I- binary systems
    1990, Vol. 55, Issue 7, pp. 1741–1749 [Abstract]
  • Karel Eckschlager and Jiří Fusek
    Information content of the determinations of the amount of an analyte
    1988, Vol. 53, Issue 12, pp. 3021–3028 [Abstract]
  • Gabor Mező, Hana Votavová, Ferencz Hudecz, Judit Kajtár, Jaroslav Šponar and Mária Szekerke
    Conformation of branched polypeptides: The influence of relative position of leucine residues in the side chains
    1988, Vol. 53, Issue 11, pp. 2843–2853 [Abstract]
  • Stanislav Heřmánek, Tomáš Jelínek, Jaromír Plešek, Bohumil Štíbr and Jiří Fusek
    Revision of nido-2,6-C2B7H11 to the arachno-4,5-C2B7H13 structure. Determination of the structure from NMR spectra and chemical origin
    1988, Vol. 53, Issue 11, pp. 2742–2752 [Abstract]
  • Hana Votavová, Jana Pírková, Vladimír Gut and Karel Bláha
    Sequential oligopeptides containing lysene: Synthesis, circular dichroism, conformation and complexes with DNA
    1988, Vol. 53, Issue 2, pp. 389–410 [Abstract]
  • Bohumil Štíbr, Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek, Konstantin A. Solntsev and Nicolai T. Kuznetsov
    Symmetrical isomers of arachno-5,5'-X-(6,9-C2B8H13)2 (X = O and OSO2O) compounds
    1987, Vol. 52, Issue 4, pp. 957–959 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Chemistry of compounds with the 1-carba-closo-dodecaborane(12) framework
    1986, Vol. 51, Issue 4, pp. 819–829 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek and Bohumil Štíbr
    Synthesis and reactions of 1,2-dicarba-closo-dodecarborane-1-yl tetrahydroborate(1-)
    1986, Vol. 51, Issue 1, pp. 81–89 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Preparation of 7-substituted 7-carba-nido-undecaboranes(12)
    1985, Vol. 50, Issue 6, pp. 1376–1382 [Abstract]
  • Hana Votavová, Ferenc Hudecz, Judit Kajtár, Jaroslav Šponar, Karel Bláha and Mária Szekerke
    Conformation of branched polypeptides based on poly(L-lysine): The effect of terminal amino acids in the branches
    1985, Vol. 50, Issue 1, pp. 228–244 [Abstract]
  • Jaromír Plešek, Karel Baše, František Mareš, František Hanousek, Bohumil Štíbr and Stanislav Heřmánek
    Potential uses of metallocarborane sandwich anions for analysis, characterization and isolation of various cations and organic bases
    1984, Vol. 49, Issue 12, pp. 2776–2789 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Eva Drdáková, Stanislav Heřmánek and Bohumil Štíbr
    A convenient preparation of 1-CB11H12- and its C-amino derivatives
    1984, Vol. 49, Issue 7, pp. 1559–1562 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    A [8,8'-μ-I-3-Co(1,2-C2B9H10)2] metallacarborane complex with a iodonium bridge. Evidence for a bromonium analogue
    1984, Vol. 49, Issue 6, pp. 1492–1496 [Abstract]
  • Jiří Fusek, Oldřich Štrouf and Karel Kuchynka
    Approximation of adsorption heats of carbon monoxide on transition metals by means of an empirical model
    1983, Vol. 48, Issue 10, pp. 2735–2739 [Abstract]
  • Otomar Kříž, Jiří Fusek and Bohuslav Čásenský
    Structure of sodium tetracaprolactamatoaluminate. 1H NMR spectra of sodium isobutylcaprolactamatoaluminates
    1983, Vol. 48, Issue 10, pp. 2728–2734 [Abstract]
  • Otomar Kříž, Jiří Fusek and Bohuslav Čásenský
    Sodium tetralactamatoaluminates(1-). A study of valence vibrations of lactam grouping in sodium 6-hexanelactamato-isobutylaluminates(1-)
    1983, Vol. 48, Issue 8, pp. 2188–2196 [Abstract]
  • Zuzana Hausenblasová, Hana Votavová, Karel Bláha and Jaroslav Šponar
    Thermal denaturation of complexes of DNA with sequential and random lysine containing polypeptides
    1983, Vol. 48, Issue 2, pp. 679–689 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Hana Votavová, Ferenc Hudecz, Jaroslav Šponar, Karel Bláha and Mária Szekerke
    Conformation of branched polypeptides based on poly(L-lysine). Effect of the ionic strength and of the presence of alcohols
    1982, Vol. 47, Issue 12, pp. 3437–3446 [Abstract]
  • Oldřich Štrouf, Jiří Fusek and Karel Kuchynka
    Approximation of the adsorption heats of hydrogen on transition metals by means of an empirical model
    1982, Vol. 47, Issue 9, pp. 2363–2367 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Stanislav Heřmánek, Karel Baše, Lee J. Todd and W. F. Wright
    Synthesis and characteristics of sulfur interligand bridge-derivatives and of some S-substituted compounds in the (C2B9H11)2Co- series. Conformations of (C2B9H11)2Mx- metallocarboranes
    1981, Vol. 46, Issue 11, pp. 2818–2833 [Abstract]
  • Oldřich Štrouf, Karel Kuchynka and Jiří Fusek
    Modelling of the catalytic Fischer-Tropsch synthesis by pattern recognition. Chemisorption and dissociation of carbon monoxide on metals
    1981, Vol. 46, Issue 10, pp. 2336–2344 [Abstract]
  • Karel Kuchynka, Jiří Fusek and Oldřich Štrouf
    Modelling of Fischer-Tropsch catalytic synthesis by pattern recognition method. Chemisorption of hydrogen on metals
    1981, Vol. 46, Issue 10, pp. 2328–2335 [Abstract]
  • Jaromír Plešek, Zbyněk Plzák, Jiří Stuchlík and Stanislav Heřmánek
    Synthesis of B-alkyl derivatives of o-carborane by alkylation under electrophilic conditions; Scope and limitation
    1981, Vol. 46, Issue 8, pp. 1748–1763 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Syntheses and properties of substituted icosahedral carborane thiols
    1981, Vol. 46, Issue 3, pp. 687–692 [Abstract]
  • Oldřich Štrouf, Jiří Fusek and Karel Kuchynka
    Modelling of catalytic activity of transition metals in hydrogenolysis of ethane by the pattern recognition approach
    1981, Vol. 46, Issue 1, pp. 65–71 [Abstract]
  • Oldřich Štrouf and Jiří Fusek
    Simplex search for mathematical representation of chemical class structure
    1981, Vol. 46, Issue 1, pp. 58–64 [Abstract]
  • Karel Kuchynka, Jiří Fusek and Oldřich Štrouf
    Catalytic activity of transition metals in hydrogenolysis of ethane calculated by the simplex method
    1981, Vol. 46, Issue 1, pp. 52–57 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Synthesis and properties of some icosahedral carborane B,B'-dithiols
    1980, Vol. 45, Issue 6, pp. 1775–1779 [Abstract]
  • Hana Votavová, Ferenc Hudecz, Judit Kajtár, Mária Szekerke, Jaroslav Šponar and Karel Bláha
    Conformation of branched polypeptides based on poly(L-lysine): Circular dichroism study
    1980, Vol. 45, Issue 3, pp. 941–949 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Synthesis and properties of 1-HSCH2-1,2-C2B10H11
    1979, Vol. 44, Issue 9, pp. 2769–2771 [Abstract]
  • Oldřich Štrouf and Jiří Fusek
    Model intrinsic dimensionality in pattern recognition analysis of structural data of complex hydrides
    1979, Vol. 44, Issue 5, pp. 1370–1378 [Abstract]
  • Jiří Fusek and Oldřich Štrouf
    Estimation of the stability of complex hydrides by a pattern-recognition classification method
    1979, Vol. 44, Issue 5, pp. 1362–1369 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Experimental evaluation of charge distribution on particular skeletal atoms in icosahedral carboranes by means of HS-derivatives
    1979, Vol. 44, Issue 1, pp. 24–33 [Abstract]
  • Otomar Kříž, Jiří Fusek and Petr Trška
    A study of the structure of sodium monohydro-tris(2-methoxyethoxo)borate
    1978, Vol. 43, Issue 12, pp. 3130–3139 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Four new (CH3)2S·C2B9H11 isomers
    1978, Vol. 43, Issue 11, pp. 2862–2868 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Chemistry of 9-mercapto-1,7-dicarba-closo-dodecaborane
    1978, Vol. 43, Issue 5, pp. 1332–1338 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Introduction of an HS-group into electron donor positions in icosahedral heteroboranes. A new method for the preparation of metallocarborane sandwich compounds with o-phenylene bridges
    1978, Vol. 43, Issue 5, pp. 1325–1331 [Abstract]