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Collect. Czech. Chem. Commun. 1996, 61, 1585-1599
https://doi.org/10.1135/cccc19961585

A Simplified Model for Calculation of the Gibbs Energy of Mixing in Crystals: Thermodynamic Theory, Restrictions and Applicability

Christomir Christov

Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria

Crossref Cited-by Linking

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  • Zhang Yulong, Li Yun, Guo Hongfei, Liu Xiuwu, Xu Dong, Cao Jilin: Solubility Measurement and Calculation of the Quaternary System KCl–KBr–NaCl–NaBr–H2O at 323.15 K. J. Chem. Eng. Data 2023, 68, 3467. <https://doi.org/10.1021/acs.jced.3c00480>
  • Tsenov Tsvetan, Donchev Stanislav, Christov Christomir: Development of accurate chemical thermodynamic database for geochemical storage of nuclear waste. Part III: Models for predicting solution properties and solid-liquid equilibrium in cesium binary and mixed systems. BR 2022, 17, 407. <https://doi.org/10.3897/biorisk.17.77523>
  • Cui Rui-Zhi, Wang Wei, Yang Lei, Sang Shi-Hua: Phase Diagram of Quaternary System NaBr–KBr–CaBr2–H2O at 323 K. Russ. J. Phys. Chem. 2018, 92, 475. <https://doi.org/10.1134/S003602441803024X>
  • Cui Rui-Zhi, Wang Zhou-Chi, Xu Jin-Shu, Sang Shi-Hua: Measurements and calculations of solid-liquid equilibria in the quaternary system KBr–CaBr2–MgBr2–H2O at (298 and 323) K. Fluid Phase Equilibria 2017, 450, 140. <https://doi.org/10.1016/j.fluid.2017.07.019>
  • Gao Dandan, Li Dongdong, Li Wu: Solubility of RbCl and CsCl in pure water at subzero temperatures, heat capacity of RbCl(aq) and CsCl(aq) at T = 298.15 K, and thermodynamic modeling of RbCl + H 2 O and CsCl + H 2 O systems. The Journal of Chemical Thermodynamics 2017, 104, 201. <https://doi.org/10.1016/j.jct.2016.09.031>
  • Krumgalz B. S.: Temperature Dependence of Mineral Solubility in Water. Part I. Alkaline and Alkaline Earth Chlorides. Journal of Physical and Chemical Reference Data 2017, 46. <https://doi.org/10.1063/1.5006028>
  • Cui Rui-Zhi, Zhang Ting-Ting, Wang Wei, Sang Shi-Hua: Solid-liquid equilibria in the ternary system NaBr–KBr–H2O at 398 K. Russ. J. Phys. Chem. 2017, 91, 1775. <https://doi.org/10.1134/S0036024417090278>
  • Cui Rui-Zhi, Yang Lei, Zhang Ting-Ting, Zhang Xue-Ping, Sang Shi-Hua: Measurements and calculations of solid–liquid equilibria in the quaternary system NaBr–KBr–Na2SO4–K2SO4–H2O at 298 K. Calphad 2016, 54, 117. <https://doi.org/10.1016/j.calphad.2016.06.005>
  • Mazloumi Seyed Hossein: An ion-based nonelectrolyte NRTL-NRF for aqueous electrolyte solutions. Calphad 2015, 51, 299. <https://doi.org/10.1016/j.calphad.2015.10.012>
  • Kulik D.A.: Dual-thermodynamic estimation of stoichiometry and stability of solid solution end members in aqueous–solid solution systems. Chemical Geology 2006, 225, 189. <https://doi.org/10.1016/j.chemgeo.2005.08.014>
  • Christov Christomir: Thermodynamics of formation of double salts and mixed crystals from aqueous solutions. The Journal of Chemical Thermodynamics 2005, 37, 1036. <https://doi.org/10.1016/j.jct.2005.01.008>
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  • Christov Christomir: Thermodynamic study of the Na-Cu-Cl-SO - H O system at the temperature 298.15 K. The Journal of Chemical Thermodynamics 2000, 32, 285. <https://doi.org/10.1006/jcht.1999.0564>
  • Christov Christomir: Thermodynamic study of the KCl-K2SO4-K2Cr2O7-H2O system at the temperature 298.15 K. Calphad 1998, 22, 449. <https://doi.org/10.1016/S0364-5916(99)00004-8>