Collect. Czech. Chem. Commun. 2002, 67, 569-576
https://doi.org/10.1135/cccc20020569

Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications

Jaromír Plešeka,*, Ivana Císařováb and Jaroslav Bačkovskýa

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež, Czech Republic
b Department of Inorganic Chemistry, Charles University, 128 40 Prague 2, Czech Republic

Individual author index pages


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    1995, Vol. 60, Issue 5, pp. 820–828 [Abstract]
  • Jaromír Plešek, Farzaneh Hosseinpour Rajabi, Veena Vangani and Jiří Fusek
    Constitution and Properties of the 8,8'-μ-(H2NO)=(1,2-C2B9H10)2-3-Co Bridged Cobaltaborane
    1994, Vol. 59, Issue 6, pp. 1326–1336 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Stanislav Heřmánek, Jiří Fusek and Hana Votavová
    Constitution and HPLC Resolution of Enantiomers of the [8,4'-μ-R2N-commo-(1,2-C2B9H10)2-3-Co] Complexthe Third Isomer of Nitrogen-Bridged Bis
    1994, Vol. 59, Issue 2, pp. 374–380 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Jiří Fusek and Hana Votavová
    Asymmetric Cobaltacarboranes [6,6'-μ-R-S(1,7-C2B9H10)2-2-Co] with a Monosulfur Bridge between Ligands and HPLC Resolution of the Enantiomers
    1993, Vol. 58, Issue 12, pp. 2936–2943 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, František Mareš and Stanislav Heřmánek
    Unique Dialkylsulfonio-Methylation of the 7,8-C2B9H12(-) Ion to the 9-R2S-CH2-7,8-C2B9H11 Zwitterions by Formaldehyde and Dialkyl Sulfides. General Synthesis of the Compounds 10-R2E-7,8-C2B9H11 (E = O, S)
    1993, Vol. 58, Issue 7, pp. 1534–1547 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Petr Maloň
    Synthesis and Properties of (±)- and (+)-4-MeS-3-C2H5-1,2,3-C2CoB9H10
    1993, Vol. 58, Issue 5, pp. 1087–1092 [Abstract]
  • Dalimil Dvořák, David Šaman, Zdeněk Arnold, Ivana Císařová and Václav Petříček
    Cycloaddition Reactions of Arylmethylenemalonaldehydes with Olefins
    1992, Vol. 57, Issue 11, pp. 2337–2358 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Otomar Kříž, Zbyněk Plzák and Jaromír Plešek
    Triethylamine borane - a stable, efficient and safe reductant for transforming carboxylic acids to primary alcohols
    1990, Vol. 55, Issue 12, pp. 2956–2962 [Abstract]
  • Ladislav Lešetický, Stanislav Smrček, Vladimír Sváta, Jana Podlahová, Jaroslav Podlaha and Ivana Císařová
    The synthesis and X-ray structure of 3,7-diiododibenzosuberone. Synthesis of 3,7-diiodoamitriptyline
    1990, Vol. 55, Issue 11, pp. 2677–2684 [Abstract]
  • Stanislav Heřmánek, Tomáš Jelínek, Jaromír Plešek, Bohumil Štíbr and Jiří Fusek
    Revision of nido-2,6-C2B7H11 to the arachno-4,5-C2B7H13 structure. Determination of the structure from NMR spectra and chemical origin
    1988, Vol. 53, Issue 11, pp. 2742–2752 [Abstract]
  • Jiří Brynda, Bohumil Kratochvíl and Ivana Císařová
    The determination of crystal structure of chromium(II) phosphite dihydrate, CrHPO3 2 H2O
    1987, Vol. 52, Issue 7, pp. 1742–1747 [Abstract]
  • Bohumil Štíbr, Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek, Konstantin A. Solntsev and Nicolai T. Kuznetsov
    Symmetrical isomers of arachno-5,5'-X-(6,9-C2B8H13)2 (X = O and OSO2O) compounds
    1987, Vol. 52, Issue 4, pp. 957–959 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Chemistry of compounds with the 1-carba-closo-dodecaborane(12) framework
    1986, Vol. 51, Issue 4, pp. 819–829 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek and Bohumil Štíbr
    Synthesis and reactions of 1,2-dicarba-closo-dodecarborane-1-yl tetrahydroborate(1-)
    1986, Vol. 51, Issue 1, pp. 81–89 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Preparation of 7-substituted 7-carba-nido-undecaboranes(12)
    1985, Vol. 50, Issue 6, pp. 1376–1382 [Abstract]
  • Jaromír Plešek, Karel Baše, František Mareš, František Hanousek, Bohumil Štíbr and Stanislav Heřmánek
    Potential uses of metallocarborane sandwich anions for analysis, characterization and isolation of various cations and organic bases
    1984, Vol. 49, Issue 12, pp. 2776–2789 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Eva Drdáková, Stanislav Heřmánek and Bohumil Štíbr
    A convenient preparation of 1-CB11H12- and its C-amino derivatives
    1984, Vol. 49, Issue 7, pp. 1559–1562 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    A [8,8'-μ-I-3-Co(1,2-C2B9H10)2] metallacarborane complex with a iodonium bridge. Evidence for a bromonium analogue
    1984, Vol. 49, Issue 6, pp. 1492–1496 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Stanislav Heřmánek, Karel Baše, Lee J. Todd and W. F. Wright
    Synthesis and characteristics of sulfur interligand bridge-derivatives and of some S-substituted compounds in the (C2B9H11)2Co- series. Conformations of (C2B9H11)2Mx- metallocarboranes
    1981, Vol. 46, Issue 11, pp. 2818–2833 [Abstract]
  • Jaromír Plešek, Zbyněk Plzák, Jiří Stuchlík and Stanislav Heřmánek
    Synthesis of B-alkyl derivatives of o-carborane by alkylation under electrophilic conditions; Scope and limitation
    1981, Vol. 46, Issue 8, pp. 1748–1763 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Syntheses and properties of substituted icosahedral carborane thiols
    1981, Vol. 46, Issue 3, pp. 687–692 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Synthesis and properties of some icosahedral carborane B,B'-dithiols
    1980, Vol. 45, Issue 6, pp. 1775–1779 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Synthesis and properties of 1-HSCH2-1,2-C2B10H11
    1979, Vol. 44, Issue 9, pp. 2769–2771 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Experimental evaluation of charge distribution on particular skeletal atoms in icosahedral carboranes by means of HS-derivatives
    1979, Vol. 44, Issue 1, pp. 24–33 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Four new (CH3)2S·C2B9H11 isomers
    1978, Vol. 43, Issue 11, pp. 2862–2868 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Chemistry of 9-mercapto-1,7-dicarba-closo-dodecaborane
    1978, Vol. 43, Issue 5, pp. 1332–1338 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Introduction of an HS-group into electron donor positions in icosahedral heteroboranes. A new method for the preparation of metallocarborane sandwich compounds with o-phenylene bridges
    1978, Vol. 43, Issue 5, pp. 1325–1331 [Abstract]